Main toolbar > Align Camera button (on Align flyout)
Tools menu > Align Camera
Align Camera, available from the Align flyout, lets you align a camera to a selected face normal.
Align Camera works similarly to Place Highlight, except that it operates on face normals instead of the angle of incidence, and occurs when you release the mouse button instead of dynamically acting during the mouse drag. Its purpose is to let you align a Camera viewport to a specified face normal.
Other alignment tools on the Align flyout are Align, Quick Align, Normal Align, Place Highlight, and Align to View.
To use Align Camera: