You can drag any non-tabbed toolbar to any location on the screen. At window edges, the toolbar will automatically dock itself according to the location. For example, if you drag it to the right edge of the screen, it will assume a vertical orientation.
If you drag it into the drawing window, it will float freely. You can then move it by dragging it by its title bar.
To move a toolbar:
Click and hold your mouse button over the left grip end of the toolbar (or its title bar if it is currently in the drawing area).
Drag the toolbar to the desired location.
Release the mouse button.